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The copper age comic "Web of Spiderman" volume 1 issue 100.
Front cover art for the foil comic "Web of Spiderman" volume 1 issue 100.
Back cover art for the Spiderverse comic "Web of Spiderman" volume 1 issue 100.

Web of Spider-Man #100 (May 1993, Marvel)

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First appearance of Spider-Armor MK I.

Giant sized 100th issue.

Conclusion of "My Enemy's Enemy!"