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The Copper Age comic "Web of Spiderman" volume 1 issue 19
Front cover art for the copper age comic "Web of Spiderman" volume 1 issue 19.
Back cover art for the copper age comic "Web of Spiderman" volume 1 issue 19.

Web of Spider-Man #19 Newsstand (October 1986, Marvel)

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First appearance of Humbug. 1st cameo appearance of Solo